04 October 2013

Graphene With Aroma: New Production Method Broadens Prospects for 'Magic' Material

Credit: Fig.: Advanced Materials 25 (2013). Copyright Wiley-VCH Verlag GmbH & Co. KGaA. Reproduced with permission.

New production method broadens the prospects for an improved use of the "magic material" -- many different forms are possible.

Graphene, a crystal composed of only one layer of carbon atoms arranged in a regular hexagon, is regarded as a material which is believed to be capable of performing 'miracles', in particular in the fields of electronics, sensor technology and display technology, but also in metrology. Only four years after the first successful development of graphene, its discoverers Geim and Novoselov were awarded a Nobel Prize. As the original preparation method (flaking of single atomic layers of graphite) does not offer a good prospects for broad technological use, many groups of researchers are concentrating very strongly on the development of alternative manufacturing procedures. A completely new and very flexible variant has now been developed by the group of Andrey Turchanin from the University of Bielefeld in cooperation with the University of Ulm and three departments of the Physikalisch-Technische Bundesanstalt (PTB) and this has been published in the scientific journal Advanced Materials.

In contrast to the conventional methods where graphene is manufactured, for example, by precipitation of carbon atoms from the gas phase or by thermal graphitization of silicon carbide, the scientists selected aromatic molecules as a starting point in this work. As substrates, both copper single-crystals and inexpensive polycrystalline copper foils were used. By irradiation with low-energy electrons and subsequent thermal annealing, it was then possible to convert a self-organized single-layer of the molecule biphenyl thiol, which had precipitated on the copper surface, into graphene.

To investigate the chemical and physical properties of the graphene manufactured in this way, different characterization methods from Ulm and Bielefeld universities and from PTB were applied, for example, scanning tunnelling microscopy, transmission electron microscopy, Raman spectroscopy as well as electric transport measurements at low temperatures and high magnetic fields. All these measurements confirm that graphene of excellent crystalline and electronic quality had actually been manufactured from the aromatic molecule.

The flexibility of the electron irradiation, which is possible both over large areas and also with excellent spatial resolution at small, well-defined places, now allows graphene structures of basically any form to be manufactured, e.g. quantum dots, nanoribbons or other nano-geometries with specific functionality. The selection of the temperature in the thermal conversion step also allows the degree of crystallinity and the characteristics of the graphene depending on it to be adjusted.

Additional advantages result from the versatility of the method of self-organized coating. It can be performed with different aromatic molecules which could, for example, also contain doping atoms for electronic doping of the final product. Applied in multiple layers, so-called bi-layer or multi-layer graphene could be manufactured, whose changed electronic band structure expands the potential applications of single-layer graphene. Likewise, other substrates than the copper used here (for example other metals, semiconductors, isolators) can be used. In addition, it should also be possible to manufacture graphene on any three-dimensional surfaces, as molecular self-organization also takes place on curved surfaces.

Read more: Graphene used to make graphene-copper composite that’s 500 times stronger

Dan G. Matei, Nils-Eike Weber, Simon Kurasch, Stefan Wundrack, Mirosław Woszczyna, Miriam Grothe, Thomas Weimann, Franz Ahlers, Rainer Stosch, Ute Kaiser, Andrey Turchanin. Functional Single-Layer Graphene Sheets from Aromatic Monolayers. Advanced Materials, 2013; 25 (30): 4146 DOI: 10.1002/adma.201300651


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